I love pairing silk with chinos. There's something very interesting between the femininity of the silk and the rough utility of the chinos that balances out the whole outfit.
This cashmere cardigan is so cool because of the way they manipulated the knit to become mini ruffles, that give the illusion of a strong shoulder.
Cashmere Sweater: Catherine Malandrino similar
Silk Tank: Joie similar
Chinos: All Saints similar
Booties: All Saints similar